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Showing posts with label Unit operation. Show all posts
Showing posts with label Unit operation. Show all posts

Saturday, 6 June 2015

Why we pass cold fluid to shell side and hot fluid to tube side?

If we pass hot fluid through shell then we will have a chance of heating loss to the surrounding.


However, practically this statement is not true.

The choice of shell and tube-side fluids for an heat exchanger are often governed by more demanding requirements which have implications on the safety, cost, maintenance time and feasibility of the heat exchanger and cannot be generalized as cold fluid on shell side and hot on tube-side. 

Some examples on how this choice is made might be - 

1-Frequent mechanical Cleaning - Tubeside to more fouling fluid, if mechanical cleaning is required. Note that chemical cleaning can always be done even on shell side. Mechanical cleaning on shells side however would require access to tube outer surface which in turn would require design features such bundle pullout possible / tube-tube gap/tube layout. It is more difficult than tubeside cleaning as it will require dismantling the whole exchanger. eg most Cooling water exchangers in process industry, which are frequently cleaned using hydrojetting.

2-Pressure - Tubeside to high pressure fluids (Shell side high pressure increases the thickness of shell and can have great implications on cost of the exchanger). Remember, shell cost forms the major cost of the exchanger in most cases.

3-Viscosity - Shell side to viscous fluids as turbulence, which can be more easily induced on shell side might be difficult (note viscous and fouling fluids are not essentially the same thing and are often confused as high viscosity implying high fouling). And then there are tube inserts which can give you that effect on tube-side as well.

4-Corrosive - Tubeside to corrosive fluid - Less components for it to see and eat up

5-Metallurgy - Expensive metallurgy on tubeside- Process requirements such as compatibility of your fluid or high or low temperatures might require you to use a particular metallurgy. It is always cheaper to use the more expensive metallurgy on the tubeside as it will require less of that metal.

This is not an exhaustive list and you can find more things in any chemical engineering text on heat exchangers for more info.

It gets tougher than this in real life where you might have competing requirements and this is often a choice between lesser of the two evils. To give you an example would be an  HF - Cooling water exchanger, where you will have to choose between a corrosive or fouling fluid to be kept on the shell side. 

To make things even more complicated, there might be cases such as some plants dismantle the exchangers and transport them to a different place dedicated for cleaning of exchangers for safety concerns. You therefore need much more information for this simple decision if you are designing an actual exchanger.

Source - Ankit MalhotraChemical Engineer, Experience in Heat exchanger design for Refining and Petrochem.

By another reference, it's not a good practice to always put cold fluid in the shell.

1- The most general practice is that you calculate the flow areas for both, shell and tube, and put the fluid with higher flow rate in the larger flow area. Otherwise, the pressure drop will shoot up, resulting in a poor design.

2- If any fluid is corrosive, you try and put it in the tube (This way, you only have to clean the inner surface of the tube. On the other hand, if it were in the shell, you'd have to clean the outer surface of tube as well as the inner surface of shell).

3- Generally hot fluids result in scale formation, and because of cleaning reasons explained above, they are put in the tubes.

So, it totally depends on the application, and as such there is no general rule.

Saturday, 18 October 2014

ULTRAFILTRATION, NANOFILTRATION AND REVERSE OSMOSIS

What is filtration? 

Filtration is a process of removing particulate matter from water by forcing the water through a porous media. This porous media can be natural, in the case of sand, gravel and clay, or it can be a membrane wall made of various materials. Sometimes, large particles are settled before filtration; this is called sedimentation.


What is ultrafiltration? 

An ultrafiltration filter has a pore size around 0.01 micron. A microfiltration filter has a pore size 
around 0.1 micron, so when water undergoes microfiltration, many microorganisms are removed, but viruses remain in the water. Ultrafiltration would remove these larger particles, and may remove some viruses. Neither microfiltration nor ultrafiltration can remove dissolved substances unless they are first adsorbed (with activated carbon) or coagulated (with alum or iron salts). 

Microfiltration, Ultrafiltration, Nanofiltration, Reverse Osmosis
MF, UF, NF, RO


What is nanofiltration? 

Nanofiltration is a relatively recent membrane filtration process used most often with low total dissolved solids water such as surface water and fresh groundwater, with the purpose of softening (polyvalent cation removal) and removal of disinfection by-product precursors such as natural organic matter and synthetic organic matter.

NANOFILTRATION (NF) originates in the 1950s, where loose reverse osmosis (RO) or tight ultrafiltration (UF) membranes were used to produce potable water from saline solutions. Today, it has evolved as a membrane technology in its own right, recognising that despite the potential for NF to solve many industrial separation problems, the actual number of uses are limited by the necessity for selectivity and stability flux improvements.

A nanofiltration filter has a pore size around 0.001 micron. Nanofiltration removes most organic molecules, nearly all viruses, most of the natural organic matter and a range of salts. Nanofiltration removes divalent ions, which make water hard, so nanofiltration is often used to soften hard water. 


What is reverse osmosis? 

Reverse osmosis filters have a pore size around 0.0001 micron. After water passes through a 
reverse osmosis filter, it is essentially pure water. In addition to removing all organic molecules 
and viruses, reverse osmosis also removes most minerals that are present in the water. Reverse osmosis removes monovalent ions, which means that it desalinates the water. To understand how reverse osmosis works, it is helpful to understand osmosis.







Tuesday, 14 October 2014

What are side products of petroleum distillation?

There are no side products from petroleum distillation.  All parts of a barrel of oil that go through a distillation unit are used to make products.


Side products of petroleum distillation

Side products of petroleum distillation

Monday, 13 October 2014

Condensation

Condensation is the change of the physical state of matter from gas phase into liquid phase, and is the reverse of vaporization. It can also be defined as the change in the state of water vapor to liquid water when in contact with any surface. When the transition happens from the gaseous phase into the solid phase directly, the change is called deposition.

Distillation

Distillation is a process of separating the component substances from a liquid mixture by selective vaporization and condensation. Distillation may result in essentially complete separation (nearly pure components), or it may be a partial separation that increases the concentration of selected components of the mixture. In either case the process exploits differences in the volatility of mixture's components. In industrial chemistry, distillation is a unit operation of practically universal importance, but it is a physical separation process and not a chemical reaction.

Distillation
Laboratory display of distillation: 1: A source of heat 2: Still pot 3: Still head 4:Thermometer/Boiling point temperature 5: Condenser 6: Cooling water in 7:Cooling water out 8: Distillate/receiving flask 9: Vacuum/gas inlet 10: Still receiver 11: Heat control 12: Stirrer speed control 13: Stirrer/heat plate 14:Heating (Oil/sand) bath 15: Stirring means e.g. (shown), boiling chips or mechanical stirrer 16: Cooling bath.


Automatic Distillation
Automatic Distillation Unit for the determination of the boiling range of petroleum products at atmospheric pressure

industrial distillation tower
Diagram of a typical industrial distillation tower

industrial distillation tower
Section of an industrial distillation tower showing detail of trays with bubble caps


Evaporation

Evaporation is a type of vaporization of a liquid that occurs from the surface of a liquid into a gaseous phase that is not saturated with the evaporating substance. 

See more on vaporization

Vaporization

Vaporization


Vaporization (or vaporisation in British English) of an element or compound is a phase transition from the liquid phase to vapor. There are two types of vaporization: evaporation and boiling.
Vaporization, Evaporation, Condensation, Sublimation, Deposition, Freezing, Melting,
This diagram shows the nomenclature for the different phase transitions.


Evaporation is a phase transition from the liquid phase to vapor ( a state of substance below critical temperature and critical pressure) that occurs at temperatures below the boiling temperature at a given pressure. Evaporation usually occurs on the surface. Evaporation may occur when the partial pressure of vapor of a substance is less than the equilibrium vapour pressure.
Boiling is a phase transition from the liquid phase to gas phase that occurs at or above the boiling temperature. Boiling, as opposed to evaporation, occurs below the surface. Boiling occurs when the equilibrium vapour pressure of the substance is greater than or equal to the environmental pressure. For this reason, boiling point varies with the pressure of the environment.Evaporation is a surface phenomenon whereas boiling is a bulk phenomenon.

Sublimation is a direct phase transition from the solid phase to the gas phase, skipping the intermediate liquid phase.

Separation

In chemistry and chemical engineering, a separation process, or a separation technique, or simply a separation, is a method to achieve any mass transfer phenomenon that converts a mixture of substances into two or more distinct product mixtures, at least one of which is enriched in one or more of the mixture's constituents. In some cases, a separation may fully divide the mixture into its pure constituents. Separations are carried out based on differences in chemical properties, or physical properties such as size, shape, mass, density, or chemical affinity, between the constituents of a mixture, and are often classified according to the particular differences they use to achieve separation.


List of separation techniques

  • Adsorption, adhesion of atoms, ions or molecules of gas, liquid, or dissolved solids to a surface
  • Centrifugation and cyclonic separation, separates based on density differences
  • Chromatography separates dissolved substances by different interaction with (i.e., travel through) a material
  • Crystallization
  • Decantation
  • Demister (vapor), removes liquid droplets from gas streams
  • Distillation, used for mixtures of liquids with different boiling points
  • Drying, removes liquid from a solid by vaporisation
  • Electrophoresis, separates organic molecules based on their different interaction with a gel under an electric potential (i.e., different travel)
  • Elutriation
  • Evaporation
  • Extraction
    • Leaching
    • Liquid-liquid extraction
    • Solid phase extraction
  • Flotation
    • Dissolved air flotation, removes suspended solids non-selectively from slurry by bubbles that are generated by air coming out of solution
    • Froth flotation, recovers valuable, hydrophobic solids by attachment to air bubbles generated by mechanical agitation of an air-slurry mixture, which float, and are recovered
    • Deinking, separating hydrophobic ink particles from hydrophilic paper pulp in paper recycling
  • Flocculation, separates a solid from a liquid in a colloid, by use of a flocculant, which promotes the solid clumping into flocs
  • Filtration – Mesh, bag and paper filters are used to remove large particulates suspended in fluids (e.g., fly ash) while membrane processes including microfiltration,ultrafiltration, nanofiltration, reverse osmosis, dialysis (biochemistry) utilising synthetic membranes, separates micrometre-sized or smaller species
  • Fractional distillation
  • Fractional freezing
  • Oil-water separation, gravimetrically separates suspended oil droplets from waste water in oil refineries, petrochemical and chemical plants, natural gas processing plants and similar industries
  • Magnetic separation
  • Precipitation
  • Recrystallization
  • Sedimentation, separates using vocal density pressure differences
    • Gravity separation
  • Sieving
  • Stripping
  • Sublimation
  • Vapor-liquid separation, separates by gravity, based on the Souders-Brown equation
  • Winnowing
  • Zone refining

Separations based on phase equilibria
gas-liquidgas-solidliquid-solidliquid-liquidsupercritical fluid-solidsupercritical fluid-liquid
distillationadsorptionprecipitationextractionsupercritical-fluid chromatographysupercritical-fluid extraction
gas-liquid chromatographysublimationzone meltingpartition chromatography
foam fractionationcrystallization
ion exchange
adsorption
exclusion
clathration

Separations based on rate phenomena
barrier separationsfield separations
membrane filtrationelectrophoresis
dialysisultracentrifugation
ultrafiltrationelectrolysis
electrodialysisfield-flow fractionation
reverse osmosis

Tuesday, 30 September 2014

The Distillation of Petroleum

Distillation of Petroleum
Distillation of Petroleum
The Distillation of Petroleum

(a) This is a diagram of a distillation column used for separating petroleum fractions.

(b) Petroleum fractions condense at different temperature, depending on the number of carbon atoms in the molecules, and are drawn off from the column. The most volatile components (those with the lowest boiling points) condense at the top of the column, and the least volatile (those with the highest boiling points) condense at the bottom.